Interchange of energy

Interchange of energy

Radiant heat panel for testing precisely quantified energy exposures at National Research Council, near Ottawa, Ontario, Canada.

Thermal radiation is an important concept in thermodynamics as it is partially responsible for heat exchange between objects, as warmer bodies radiate more heat than colder ones. (Other factors are convection and conduction.) The interplay of energy exchange is characterized by the following equation:

Here, represents spectral absorption factor, spectral reflection factor and spectral transmission factor. All these elements depend also on the wavelength . The spectral absorption factor is equal to the emissivity ; this relation is known as Kirchhoff's law of thermal radiation. An object is called a black body if, for all frequencies, the following formula applies:

In a practical situation and room-temperature setting, humans lose considerable energy due to thermal radiation. However, the energy lost by emitting infrared heat is partially regained by absorbing the heat of surrounding objects (the remainder resulting from generated heat through metabolism). Human skin has an emissivity of very close to 1.0 .^[3] Using the formulas below then shows a human being, roughly 2 square meter in area, and about 307 kelvins in temperature, continuously radiates about 1000 watts. However, if people are indoors, surrounded by surfaces at 296 K, they receive back about 900 watts from the wall, ceiling, and other surroundings, so the net loss is only about 100 watts. These heat transfer estimates are highly dependent on extrinsic variables, such as wearing clothes (decreasing total thermal "circuit" conductivity, therefore reducing total output heat flux.) Only truly "grey" systems (relative equivalent emissivity/absorptivity and no directional transmissivity dependence in all control volume bodies considered) can achieve reasonable steady-state heat flux estimates through the Stefan-Boltzmann law. Encountering this "ideally calculable" situation is virtually impossible (although common engineering procedures surrender the dependency of these unknown variables and "assume" this to be the case). Optimistically, these "grey" approximations will get you close to real solutions, as most divergence from Stefan-Boltzmann solutions is very small (especially in most STP lab controlled environments).

If objects appear white (reflective in the visual spectrum), they are not necessarily equally reflective (and thus non-emissive) in the thermal infrared; e. g. most household radiators are painted white despite the fact that they have to be good thermal radiators. Acrylic and urethane based white paints have 93% blackbody radiation efficiency at room temperature^[4] (meaning the term "black body" does not always correspond to the visually perceived color of an object). These materials that do not follow the "black color = high emissivity/absorptivity" caveat will most likely have functional spectral emissivity/absorptivity dependence.

Calculation of radiative heat transfer between groups of object, including a 'cavity' or 'surroundings' requires solution of a set of simultaneous equations using the Radiosity method. In these calculations, the geometrical configuration of the problem is distilled to a set of numbers called view factors, which give the proportion of radiation leaving any given surface that hits another specific surface. These calculations are important in the fields of solar thermal energy, boiler and furnace design and raytraced computer graphics.